Product ID:20-9517 FREON 12
MSDS Date:08/21/1989
FSC:6830
NIIN:00-106-1656
MSDS Number: CCMNQ

VALVOLINE OIL CO SUBSIDIARY OF ASHLAND OIL INC.

200 E MAIN ST
LEXINGTON, KY 40512
US

Emergency Phone: 800-ASHLAND/800-274-5263

Info Phone: 606-264-7000/7616;FAX 601-429-0537

Cage: 72527

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

DICHLORODIFLUOROMETHANE (SARA 313) (CERCLA)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: >95%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:TLV:1000 PPM.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:CAN CAUSE SEVERE
IRRIT,REDNESS,TEARING,BLURRED VISION.SKIN:CONTACT W/LIQUID CAN
RESULT IN FREEZING OF TISSUE.BREATH:EXCESSIVE VAP INHAL CAN CAUSE
NASAL/RESP IRRIT,CNS EFFECTS INCLUDING DIZZ,WEAK,F
TG,NAU,HEAD,POSSIBLE UNCONSC,EVEN DEATH.INGEST:CAN CAUSE
GASTROINTESTINAL IRRIT,NAU,VOMIT,DIARRHEA.
Effects of Overexposure:SEVERE EYE IRRIT,REDNESS,TEARING,BLURRED
VISION. FREEZING OF TISSUES. NASAL/RESPIRATORY IRRIT,CNS
EFFECTS-DIZZINESS,WEAKNESS,FTG,NAU,HEADACHE,POSSIBLE UNCONSC,DEATH.
GASTROINTESTINAL IRRIT,NAU,VOMIT,D IARRHEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:SLOWLY WARM AFFECTED AREA W/TEPID WATER.GET MED
ATTN.EYE:FLUSH W/LG AMTS OF WATER LIFTING UPPER/LOWER LIDS
OCCASIONALLY.GET MED ATTN.INGEST:DO NOT INDUCE VOMIT.KEEP PERSON
WARM/QUIET.GET MED ATTN .INHAL:REMOVE TO FRESH AIR.BREATH
DIFFIADMIN OXY;BREATH STOP GIVE ART RESP.KEEP WARM/QUIET.GET MED
ATTN.DO NOT GIVE STIMULANTS.EPINEPHRINE OR EPHEDRINE MAY ADVERSELY
AFFECT THE HEART W/FATAL RESULTS.

Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. HMIS:USE
APPROPRIATE FIRE EXTINGUISHING MEDIA FOR SURROUNDING FIRE/MATLS.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN
POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES.

Spill Release Procedures:SM:VENTILATE AREA.ALLOW TO EVAPORTE.LG:ALLOW
TO EVAPORATE.PERSON NOT WEARING PROT EQPMT SHOULD BE EXCLUDED FROM
AREA TIL REPAIRED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNR OF THIS MATL MAY BE HAZ WHEN
EMPTIED SINCE THEY RETAIN PROD RESIDUE(VAP,LIQ,SOLID).ALL HAZ
PRECAUTION GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:WORKPLACE EXPO PROD/COMPONENT LIMITS
EXCEEDED,NIOSH/MSHA APPROVE AIR SUPPLIED RESP ADVISED IN ABSENCE OF
PROPER ENVIRO CNTRL.OSHA REGS PERMIT OTHER NIOSH/MSHA RESP UNDER
SPEC CONDITIONS.(SEE SAF EQPMT SUPPLIER).IMPLEMENT ENGIN/ADMIN
CNTRL.
Ventilation:PROIVDE SUFFICIENT MECHANICAL(GEN &/OR LOC
EXHAUST)VENTILATION TO MAINTAIN EXPO BELOW TLVS.
Protective Gloves:RESISTANT GLOVES:POLYVINYL ALCOHOL.
Eye Protection:CHEM SPLASH GOGG,OTHER OSHA TYPE GLASSES
Other Protective Equipment:NORMAL WORK CLOHTING COVERING ARMS/LEGS.
Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE.
Supplemental Safety and Health

HCC:G3
Boiling Pt:B.P. Text:-22F,-30C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:4700MM@77F
Vapor Density:4.3
Spec Gravity:1.310 @77F
pH:NP
Viscosity:NP
Evaporation Rate & Reference:FASTER THAN ETHER.
Solubility in Water:NP
Appearance and Odor:CLEAR, COLORLESS GAS, HOMOG SOLN.
Percent Volatiles by Volume:100
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/ALKALI METALS, POWDERED METALS, ALKALINE METALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATLS:HYDROGEN
CHLORIDE, PHOSGENE, HYDROGEN FLUORIDE, ETC.

Waste Disposal Methods:CHEM SUBJ TO REPORTING REQMTS OF SEC 313 SARA
TITLE III. SM SPILL:ALLOW MATERIAL TO EVAPORTE.LG SPILL:RETURN TO
SUPPLIER FOR RECLAMATION. HMIS:FOLLOW ALL APPLICABLE FED/STATE/LOC
REGS.

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